Look for Classic Outlook in Microsoft's instructions for how to create signatures for Microsoft Outlook.
The Microsoft Outlook Office 365 desktop app has a bug that prevents Google Workspace Sync users from setting a default signature.
To fix this:
- Close Microsoft Outlook.
- Download, extract, and run this .reg file. Tell the prompts "Yes". This disables remote signatures in Outlook.
- Once the reg file is run you should get a message that says successfully added to the registry.
- Open Microsoft Outlook and set your default signatures.